In the electrochemical cell
$\mathrm{Z}\mathrm{n}\left|\mathrm{Z}\mathrm{n}\mathrm{S}{\mathrm{O}}_4\right(0.01\mathrm{M}\left)\left|\right|\mathrm{C}\mathrm{u}\mathrm{S}{\mathrm{O}}_4\right(1.0\mathrm{M}\left)\right|\mathrm{C}\mathrm{u},$ the emf of this Daniel cell is ${\mathrm{E}}_1$ . When the concentration of $\mathrm{Z}\mathrm{n}\mathrm{S}{\mathrm{O}}_4$ is changed to 1.0M and that of $\mathrm{C}\mathrm{u}\mathrm{S}{\mathrm{O}}_4$ changed to 0.01M, the emf changes to ${\mathrm{E}}_2$ . From the followings, which one is the relationship between ${\mathrm{E}}_1$ and ${\mathrm{E}}_2$ ?
(Given, $\frac{\mathrm{R}\mathrm{T}}{\mathrm{F}}=0.059$ )