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Question: Answered & Verified by Expert
In the following reaction
Aldehyde+AlcoholHClAcetal
Aldehyde  Alcohol
HCHO t-BuOH
CH3CHO  MeOH
The best combination is:
ChemistryAldehydes and KetonesJEE MainJEE Main 2019 (12 Jan Shift 1)
Options:
  • A HCHO and MeOH
  • B CH3CHO and t-BuOH
  • C CH3CHO and MeOH
  • D HCHO and t-BuOH
Solution:
1626 Upvotes Verified Answer
The correct answer is: HCHO and MeOH

Formation of an acetal occurs when the hydroxyl group of a hemiacetal becomes protonated and is lost as water. The carbocation that is produced is then rapidly attacked by a molecule of alcohol. Loss of the proton from the attached alcohol gives the acetal.

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