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In the reaction, $A \rightarrow$ products, If the concentration of the reactant is doubled rate of the reaction remains unchanged. The order of the reaction with respect to $\mathrm{A}$ is
ChemistryChemical KineticsAP EAMCETAP EAMCET 2022 (08 Jul Shift 1)
Options:
  • A $1$
  • B $2$
  • C $0.5$
  • D $0$
Solution:
1304 Upvotes Verified Answer
The correct answer is: $0$
$\mathrm{r}_1=\mathrm{k}[\mathrm{A}]^{\mathrm{n}}$ and $\mathrm{r}_2=\mathrm{k}[2 \mathrm{~A}]^{\mathrm{n}}$
$\because \quad \mathrm{r}_1=\mathrm{r}_2 \quad \therefore \mathrm{k}[\mathrm{A}]^{\mathrm{n}}=\mathrm{k}(2[\mathrm{~A}])^{\mathrm{n}}$
or, $2^n=1$
or, $2^{\mathrm{n}}=2^{\circ} \Rightarrow \mathrm{n}=0$
It is a zero order reaction.

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