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In which of the following reactions, an increase in the volume of the container will favour the formation of products?
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$2 \mathrm{NO}_2(\mathrm{g}) \rightleftharpoons 2 \mathrm{NO}(\mathrm{g})+\mathrm{O}_2$ (g)
$2 \mathrm{NO}_2(\mathrm{g}) \rightleftharpoons 2 \mathrm{NO}(\mathrm{g})+\mathrm{O}_2$ (g)
Volume $\uparrow P \downarrow$, reaction proceeds in which direction where the number of moles of gases increases.
$2 \mathrm{NO}_2(\mathrm{~g}) \rightleftharpoons 2 \mathrm{NO}(\mathrm{g})+\mathrm{O}_2(\mathrm{~g})$
$\Delta \mathrm{n}_{\mathrm{g}}=(2+1)-2=1$
$2 \mathrm{NO}_2(\mathrm{~g}) \rightleftharpoons 2 \mathrm{NO}(\mathrm{g})+\mathrm{O}_2(\mathrm{~g})$
$\Delta \mathrm{n}_{\mathrm{g}}=(2+1)-2=1$
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