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Question: Answered & Verified by Expert
...................... is a low spin complex.
ChemistryCoordination CompoundsNEET
Options:
  • A NiCN42-
  • B CoF63-
  • C NiCl42-
  • D FeF63-
Solution:
2834 Upvotes Verified Answer
The correct answer is: NiCN42-
NiCN42- is a low spin complex. Oxidation state of Ni in NiCN42- is +2 .

Ni=Ar3d8 4s2

Ni2+=Ar3d8



CN- being strong field ligand causes pairing of 3d -electrons. Thus, one of the 3d orbital becomes empty for CN- ion.

Here, the complex formed involves the inner n-1d orbitals for hybridisation. So, the complex is called inner orbital complex.

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