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Match List I (Equations) with List II (Types of process) and select the correct option.
Codes:
$\begin{array}{llll}\mathrm{A} & \mathrm{B} & \mathrm{C} & \mathrm{D} \\ \end{array}$
Options:
Codes:
$\begin{array}{llll}\mathrm{A} & \mathrm{B} & \mathrm{C} & \mathrm{D} \\ \end{array}$
Solution:
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Verified Answer
The correct answer is:
4 1 2 3
(A) If $\mathrm{k}_{\mathrm{p}}>\mathrm{Q}$ and goes in forward direction than reaction is spontaneous
(B) Given, $\Delta G^{\circ} < R T \ln Q$, thus, $\Delta G^{\circ}=+$ ve and hence, the reaction is nonspontaneous.
(C) At equilibrium, $K_{p}=Q$
(D) $T>\frac{\Delta H}{\Delta S}$
or $T \Delta S=\Delta H$
This is valid condition for spontaneous endothermic reactions (as $\Delta G \geq \Delta H-T \Delta S$ )
(B) Given, $\Delta G^{\circ} < R T \ln Q$, thus, $\Delta G^{\circ}=+$ ve and hence, the reaction is nonspontaneous.
(C) At equilibrium, $K_{p}=Q$
(D) $T>\frac{\Delta H}{\Delta S}$
or $T \Delta S=\Delta H$
This is valid condition for spontaneous endothermic reactions (as $\Delta G \geq \Delta H-T \Delta S$ )
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