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Question: Answered & Verified by Expert
Match the column I with column II and mark the appropriate choice.
 
  Column I   Column II
(p) H2g+Br2g2HBrg (i) ΔH=ΔU-2RT
(q) PCl5gPCl3g+Cl2g (ii) ΔH=ΔU+3RT
(r) N2g+3H2g2NH3g (iii) ΔH=ΔU
(s) 2N2O5g4NO2g+O2g (iv) ΔH=ΔU+RT
ChemistryThermodynamics (C)JEE Main
Options:
  • A (p)-(iii), (q)-(i), (r)-(ii), (s)-(iv)
  • B (p)-(iii), (q)-(iv), (r)-(i), (s)-(ii)
  • C (p)-(ii), (q)-(i), (r)-(iv), (s)-(iii)
  • D (p)-(iv), (q)-(ii), (r)-(i), (s)-(iii)
Solution:
1432 Upvotes Verified Answer
The correct answer is: (p)-(iii), (q)-(iv), (r)-(i), (s)-(ii)
(p) Δng=2-2=0; hence ΔH=ΔU

(q) Δng=2-1=1; hence ΔH=ΔU+RT

(r) Δng=2-4=-2; hence ΔH=ΔU-2RT

(s) Δng=5-2=3; hence ΔH=ΔU+3RT

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