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Question: Answered & Verified by Expert
Match the List I with List II and select the correct answer using the codes given below the lists?
 
List I (Reaction of LiAlH4 with acid derivatives)
 
List II (Products)

(p)

C6H5CH2COOCH3

1.

PhCH2CH2NHMe

(q)


2.

PhCH2OH

(r)

PhCOCl

3.

C6H5CH2CH2OH+HOCH3

(s)

PhCH2CONHMe

4.

ChemistryAlcohols Phenols and EthersNEET
Options:
  • A (p)-3, (q)-4, (r)-1, (s)-2
  • B (p)-3, (q)-4, (r)-2, (s)-1
  • C (p)-1, (q)-2, (r)-3, (s)-4
  • D (p)-2, (q)-3, (r)-1, (s)-4
Solution:
1105 Upvotes Verified Answer
The correct answer is: (p)-3, (q)-4, (r)-2, (s)-1
(p) Esters on reduction form alcohols 1° is always obtained from acid portion of the esters.
C6H5CH2COOCH3LiAlH4C6H5CH2CH2OH+HOCH3
(q) Anhydrides on reduction form two equivalents of -CH2OH .

(r) PhCOClLiAlH4PhCH2OH+HCl
(s) PhCH2CONHMeLiAlH4PhCH2CH2NHMe

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