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Question: Answered & Verified by Expert
\(\mathrm{BrF}_3\) self ionises as following
Chemistryp Block Elements (Group 15, 16, 17 & 18)WBJEEWBJEE 2023
Options:
  • A \(2 \mathrm{BrF}_3 \rightleftharpoons \mathrm{BrF}^{+}+\mathrm{BrF}_5^{-}\)
  • B \(2 \mathrm{BrF}_3 \rightleftharpoons \mathrm{BrF}_2^{+}+\mathrm{BrF}_4^{-}\)
  • C \(2 \mathrm{BrF}_3 \rightleftharpoons \mathrm{BrF}_4^{+}+\mathrm{BrF}_2^{-}\)
  • D \(2 \mathrm{BrF}_3 \rightleftharpoons \mathrm{BrF}_3^{+}+\mathrm{BrF}_3^{-}\)
Solution:
2093 Upvotes Verified Answer
The correct answer is: \(2 \mathrm{BrF}_3 \rightleftharpoons \mathrm{BrF}_2^{+}+\mathrm{BrF}_4^{-}\)
Hint : \(2 \mathrm{BrF}_3 \rightleftharpoons \mathrm{BrF}_2^{+}+\mathrm{BrF}_4^{-}\)(Relatively more stable structures.)

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