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$\mathrm{Mg}^{2+}$ is isoelectronic with
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$\mathrm{Na}^{+}$
Isoelectronic species have same number of electron. $\mathrm{Mg}^{2+}$ and $\mathrm{Na}^{+}$both have 10 electrons hence, they are isoelectronic species.
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