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Molecular bromine on reaction with three moles of molecular fluorine produces an inter halogen compound. The total number of lone pairs at the central halogen atom is
Chemistryp Block Elements (Group 15, 16, 17 & 18)AP EAMCETAP EAMCET 2021 (25 Aug Shift 2)
Options:
  • A 3
  • B 2
  • C 1
  • D 0
Solution:
2162 Upvotes Verified Answer
The correct answer is: 2
Molecular bromine $\left(\mathrm{Br}_2\right)$ on reaction with 3 moles of molecular fluorine $\left(\mathrm{F}_2\right)$, it will produced 2 moles of $\mathrm{BrF}_3$.

$\mathrm{BrF}_3$ is interhalogen compound i.e. trifluorobromide.
$$
\mathrm{Br}_2(g)+3 \mathrm{~F}_2(g) \longrightarrow \underset{\text { Trifluoro-bromide }}{2 \mathrm{BrF}_3(g)}
$$
$\mathrm{BrF}_3=\frac{7 e^{-}+3 e^{-}}{2}=\frac{10}{2} e^{-}=5 e^{-}$i.e. $s p^3 d$ hybridisation.
$\mathrm{BrF}_3$ contain $3 \mathrm{Br}-\mathrm{F}^{-}$covalent bonds and 2 lone pairs.
$\mathrm{BrF}_3$ is $s p^3 d$ hybridised molecule having T-shape.


Hence, total number of lone pairs at central halogen atom is 2.

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