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Question: Answered & Verified by Expert
On the basis of crystal field theory, explain why Co(III) forms a paramagnetic octahedral complex with weak field ligands, whereas it forms a diamagnetic octahedral complex with strong field ligands.
ChemistryCoordination CompoundsNEET
Options:
  • A Weak field ligands cause a higher crystal field splitting, leading to unpaired electrons in Co(III) complexes.
  • B Weak field ligands result in a lower crystal field splitting, causing Co(III) complexes to be diamagnetic.
  • C Strong field ligands lead to a higher crystal field splitting, resulting in paired electrons in Co(III) complexes.
  • D Strong field ligands cause a lower crystal field splitting, making Co(III) complexes paramagnetic.
Solution:
2801 Upvotes Verified Answer
The correct answer is: Weak field ligands cause a higher crystal field splitting, leading to unpaired electrons in Co(III) complexes.
Correct Option is : (A)
Weak field ligands cause a higher crystal field splitting, leading to unpaired electrons in Co(III) complexes.

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