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Question: Answered & Verified by Expert
On the treatment of the following compound with a strong acid, the most susceptible site for bond cleavage is:

ChemistryGeneral Organic ChemistryJEE MainJEE Main 2018 (15 Apr Shift 2 Online)
Options:
  • A
    $\mathrm{O} 2-\mathrm{C} 3$
  • B
    O5-C6
  • C
    $\mathrm{C} 4-\mathrm{O} 5$
  • D
    $\mathrm{C} 1-\mathrm{O} 2$
Solution:
1614 Upvotes Verified Answer
The correct answer is:
O5-C6
The lone pair of electrons on $\mathrm{O} 2$ is involved in resonance with $\mathrm{C}=\mathrm{C}$. Hence $\mathrm{O} 2$ will not be protonated.
The lone pair of electrons on O5 is not involved in resonance with $\mathrm{C}=\mathrm{C}$. Hence, O5 will be protonated. Chloride ion will then attack least substituted $\mathrm{C}$ atom (C6)


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