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Question: Answered & Verified by Expert
Order of acidic nature of the following compounds is


ChemistryGeneral Organic ChemistryAIIMSAIIMS 2019 (25 May)
Options:
  • A $1>3>4>2$
  • B $1>2>4>3$
  • C $1>2>3>4$
  • D $4>3>2>1$
Solution:
2327 Upvotes Verified Answer
The correct answer is: $1>2>4>3$
Electron withdrawing group increases the acidic strength of phenols whereas electron donating group decreases the acidic strength of phenols.
$o$-Nitrophenol is little less acidic than $p$-nitrophenol due to intramolecular $\mathrm{H}$-bonding which makes loss of a proton little difficult.

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