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Out of o-nitrophenol and o-cresol which is more acidic?
ChemistryAlcohols Phenols and Ethers
Solution:
2081 Upvotes Verified Answer
o-nitrophenol is more acidic than o-cresol. Acidic character of alcohols depends upon the polarity of $\mathrm{O}-\mathrm{H}$ bond. In o-nitrophenol due to $-\mathrm{I}$ and $-\mathrm{R}$ effect of nitro-group electron density decreases in $\mathrm{O}-\mathrm{H}$ bond and polarity increases.
While in o-cresol, due to $+\mathrm{I}$ effect of $-\mathrm{CH}_3$ group electron density of $\mathrm{O}-\mathrm{H}$ bond increases. Therefore, $\mathrm{O}-\mathrm{H}$ bond becomes less polar. Hence, o-nitrophenol is more acidic than o-cresol.

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