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Copper is the most noble of the first row transition metals and occurs in small deposits in several countries. Ores of copper include chalcanthite $\left(\mathrm{CuSO}_4 \cdot 5 \mathrm{H}_2 \mathrm{O}\right)$, atacamite $\left(\mathrm{Cu}_2 \mathrm{Cl}(\mathrm{OH})_3\right)$, cuprite $\left(\mathrm{Cu}_2 \mathrm{O}\right)$, copper glance $\left(\mathrm{Cu}_2 \mathrm{~S}\right)$ and malachite $\left(\mathrm{Cu}_2(\mathrm{OH})_2 \mathrm{CO}_3\right)$. However, 80\% of the world copper production comes from the ore chalcopyrite $\left(\mathrm{CuFeS}_2\right)$. The extraction of copper from chalcopyrite involves partial roasting, removal of iron and self-reduction.Question:
In self-reduction, the reducing species is
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Copper is the most noble of the first row transition metals and occurs in small deposits in several countries. Ores of copper include chalcanthite $\left(\mathrm{CuSO}_4 \cdot 5 \mathrm{H}_2 \mathrm{O}\right)$, atacamite $\left(\mathrm{Cu}_2 \mathrm{Cl}(\mathrm{OH})_3\right)$, cuprite $\left(\mathrm{Cu}_2 \mathrm{O}\right)$, copper glance $\left(\mathrm{Cu}_2 \mathrm{~S}\right)$ and malachite $\left(\mathrm{Cu}_2(\mathrm{OH})_2 \mathrm{CO}_3\right)$. However, 80\% of the world copper production comes from the ore chalcopyrite $\left(\mathrm{CuFeS}_2\right)$. The extraction of copper from chalcopyrite involves partial roasting, removal of iron and self-reduction.Question:
In self-reduction, the reducing species is
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$\mathrm{S}^{2-}$
$\mathrm{S}^{2-}$
$\mathrm{S}^{2-}$ acts as reducing species $2 \mathrm{Cu}_2 \mathrm{O}+\mathrm{Cu}_2 \mathrm{~S}^{2-} \longrightarrow 6 \mathrm{Cu}+\mathrm{SO}_2$
Metallurgy
Conceptual
III, II, II
Metallurgy
Conceptual
III, II, II
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