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p-amino-N, N-dimethylaniline is added to a strongly acidic solution of $X$. The resulting solution is treated with a few drops of aqueous solution of $Y$ to yield blue colouration due to the formation of methylene blue. Treatment of the aqueous solution of $Y$ with the reagent potassium hexacyanoferrate(II) leads to the formation of an intense blue precipitate. The precipitate dissolves an excess addition of the reagent. Similarly, treatment of the solution of $Y$ with the solution of potassium hexacyanoferrate(III) leads to a brown colouration due to the formation of $Z$.Question:
The compound $X$, is
ChemistryAminesJEE AdvancedJEE Advanced 2009 (Paper 1)
Options:
  • A
    $\mathrm{NaNO}_3$
  • B
    $\mathrm{NaCl}$
  • C
    $\mathrm{Na}_2 \mathrm{SO}_4$
  • D
    $\mathrm{Na}_2 \mathrm{~S}$
Solution:
1173 Upvotes Verified Answer
The correct answer is:
$\mathrm{Na}_2 \mathrm{~S}$
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