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Question: Answered & Verified by Expert
PCl5 dissociates as PCl5gPCl3g+Cl2g 5 moles of PCl5 are placed in a 200 litre vessel which contains 2 moles of N2 and is maintained at 600 K. The equilibrium pressure is 2.46 atm. The equilibrium constant Kp for the dissociation of PCl5 is___×10-3. (nearest integer) (Given: R=0.082 L atm K-1 mol-1; Assume ideal gas behaviour)
ChemistryChemical EquilibriumJEE MainJEE Main 2022 (24 Jun Shift 2)
Solution:
1496 Upvotes Verified Answer
The correct answer is: 1107
PCl5    PCl3+Cl25mole       -      -     Intial moles5-x           x        x      EquilibriumTotal number of moles=5+x+nN2=7+xAs number of moles of Nitrogen gas added is 2ntotal=PVRT=2.46X 2000.082X600=107+x=10x=3Kp=310x2.46310x2.46210x2.46=1107

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