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Question: Answered & Verified by Expert
Pick out the incorrect statement
Chemistryp Block Elements (Group 15, 16, 17 & 18)JEE Main
Options:
  • A PH4+ ion is tetrahedral like the NH4+ ion and is obtained when PH3 is bonded to proton
  • B PH4I is one of the most stable salts containing the phosphonium ion. It is also more stable than ammonium salts
  • C PH4I is decomposed by water to form PH3
  • D PH3 converts silver salts in solution to silver phosphide, which subsequently reacts to give free metal
Solution:
1400 Upvotes Verified Answer
The correct answer is: PH4I is one of the most stable salts containing the phosphonium ion. It is also more stable than ammonium salts
Phosphonium iodide is less thermally stable than ammonium salts, because phosphine is less basic than ammonia and decomposition occurs at 60°C .
PH4IPH3+HI
A. PH3+HIPH4I
C. PH4I+H2OPH3+H3O++I-
D. 6Ag++PH3+3H2O6Ag+H3PO3+6H+

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