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Question: Answered & Verified by Expert
Rationalize the given statements and choose the correct option: • Lead(II) chloride reacts with Cl2to give PbCl4. • Lead(IV) chloride is highly unstable towards heat. • Lead is known not to form an iodide, PbI4.
Chemistryp Block Elements (Group 15, 16, 17 & 18)NEET
Options:
  • A The first statement describes a redox reaction where PbCl₂ is oxidized to PbCl₄. The second statement indicates that Lead(IV) chloride is thermally unstable, possibly decomposing upon heating. The third statement is true; Lead does not form a PbI₄ compound.
  • B The first statement is false as PbCl₂ reacts with Cl₂ to form PbCl₄. The second statement is true; Lead(IV) chloride is known to be highly unstable towards heat. The third statement is true; Lead does not form a PbI₄ compound.
  • C The first statement is true; PbCl₂ reacts with Cl₂ to form PbCl₄. The second statement is false as Lead(IV) chloride is known to be stable towards heat. The third statement is false; Lead does form a PbI₄ compound.
  • D The first statement is true; PbCl₂ reacts with Cl₂ to form PbCl₄. The second statement is true; Lead(IV) chloride is known to be highly unstable towards heat. The third statement is true; Lead does not form a PbI₄ compound.
Solution:
2743 Upvotes Verified Answer
The correct answer is: The first statement is false as PbCl₂ reacts with Cl₂ to form PbCl₄. The second statement is true; Lead(IV) chloride is known to be highly unstable towards heat. The third statement is true; Lead does not form a PbI₄ compound.
Correct Option is : (B)
The first statement is false as PbCl₂ reacts with Cl₂ to form PbCl₄. The second statement is true; Lead(IV) chloride is known to be highly unstable towards heat. The third statement is true; Lead does not form a PbI₄ compound.

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