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Question: Answered & Verified by Expert
The enthalpy changes for given reaction at 298 K is - x cal/mol. If the reaction occurs spontaneously at 298 K, the entropy change at that temperature
ChemistryThermodynamics (C)NEET
Options:
  • A can be negative, but numerically larger than x/298cal mol 1 K 1
  • B can be negative, but numerically smaller than x/298cal mol 1 K 1
  • C cannot be negative
  • D cannot be positive
Solution:
1217 Upvotes Verified Answer
The correct answer is: can be negative, but numerically smaller than x/298cal mol 1 K 1
ΔG=ΔH-TΔS

For a spontaneous process, ΔH-TΔS<0 .

So, ΔS> ΔH T = xcal mol 298K

Hence, ΔS is numerically smaller than x 298 cal mol 1 K 1 .

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