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Question: Answered & Verified by Expert
The gaseous products formed at cathode $(X)$ and anode $(Y)$, when an aqueous solution of sodium acetate is electrolysed are
$\begin{array}{ll}X & Y\end{array}$
ChemistryElectrochemistryAP EAMCETAP EAMCET 2017 (26 Apr Shift 1)
Options:
  • A $\begin{array}{cc}\mathrm{CO}_2 & \mathrm{C}_2 \mathrm{H}_6, \mathrm{H}_2\end{array}$
  • B $\mathrm{H}_2, \mathrm{CO}_2 \quad \mathrm{C}_2 \mathrm{H}_6$
  • C $\mathrm{H}_2 \quad \mathrm{C}_2 \mathrm{H}_6, \mathrm{CO}_2$
  • D $\mathrm{C}_2 \mathrm{H}_6, \mathrm{H}_2 \quad \mathrm{CO}_2$
Solution:
2127 Upvotes Verified Answer
The correct answer is: $\mathrm{H}_2 \quad \mathrm{C}_2 \mathrm{H}_6, \mathrm{CO}_2$
When sodium acetate is electrolysed in aqueous medium, it react as follows
$$
2 \mathrm{CH}_3 \mathrm{COONa}+2 \mathrm{H}_2 \mathrm{O} \longrightarrow 2 \mathrm{CO}_2+2 \mathrm{C}_2 \mathrm{H}_6+2 \mathrm{H}_2
$$
At anode (Y): $\mathrm{C}_2 \mathrm{H}_6+\mathrm{CO}_2$
At cathode $(\mathrm{X}): \mathrm{H}_2$

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