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The increase of pressure on system at constant temperature will lead to:
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Verified Answer
The correct answer is:
A shift of the equilibrium in the forward direction
At melting point of at (273 K = T)
dG = VdP - SdT
At constant temperature
Integrating
Pressure increased from 1 atm to P atm
is -ve, so melting in forward direction spontaneous.
Method 2 :
On Increasing P : Molecule
Ice → Water;
Since
In physical equilibrium, on increasing pressure, equilibrium shift toward more density side.
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