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Question: Answered & Verified by Expert
The ions $\mathrm{O}^{2-}, \mathrm{F}^{-}, \mathrm{Na}^{+}, \mathrm{Mg}^{2+}$ and $\mathrm{Al}^{3+}$ are isoelectronic. Their ionic radii show:
ChemistryStructure of AtomJEE Main
Options:
  • A a significant increase from $\mathrm{O}^{2-}$ to $\mathrm{Al}^{3+}$
  • B a significant decrease from $\mathrm{O}^{2-}$ to $\mathrm{Al}^{3+}$
  • C an increase from $\mathrm{O}^{2-}$ to $\mathrm{F}^{-}$and then decrease from $\mathrm{Na}^{+}$to $\mathrm{Al}^{3+}$
  • D a decrease from $\mathrm{O}^{2-}$ to $\mathrm{F}^{-}$and then increase from $\mathrm{Na}^{+}$to $\mathrm{Al}^{3+}$
Solution:
2352 Upvotes Verified Answer
The correct answer is: a significant decrease from $\mathrm{O}^{2-}$ to $\mathrm{Al}^{3+}$
Ionic radii decrease with the increase in charge on species.

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