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Question: Answered & Verified by Expert
The magnetic moment $\left(\mathrm{m}_{\mathrm{orb}}\right)$ of a revolving electron around the nucleus varies with the principal quantum number (n) as
PhysicsAtomic PhysicsJEE Main
Options:
  • A $\mathrm{m}_{\text {orb }} \propto \mathrm{n}^2$
  • B $\mathrm{m}_{\mathrm{orb}} \propto \frac{1}{\mathrm{n}^2}$
  • C $\mathrm{m}_{\mathrm{orb}} \propto \frac{1}{\mathrm{n}}$
  • D $\mathrm{m}_{\text {orb }} \propto \mathrm{n}$
Solution:
1032 Upvotes Verified Answer
The correct answer is: $\mathrm{m}_{\text {orb }} \propto \mathrm{n}$
Orbital magnetic moment can be defined as,
$\mathrm{m}_{\text {orb }}=\mathrm{iA}$
where, $\mathrm{i}=\frac{\mathrm{e}}{\mathrm{T}}, \mathrm{r}$ is the radius of the Bohr orbit, $\mathrm{A}=\pi \mathrm{r}^2$ is the area and $\mathrm{T}$ is the time period of uniform circular motion.

Now, we can make use of the Bohr's hypothesis about angular momentum:

On plugging in above into equation (1),
$\mathrm{m}_{\mathrm{orb}}=\frac{\mathrm{neh}}{4 \pi \mathrm{m}}$
Orbital magnetic moments of an electron in Bohr orbit is given by,
$\begin{aligned} & \mathrm{m}_{\text {orb }}=\mathrm{n}\left(\frac{\mathrm{eh}}{4 \pi \mathrm{m}}\right) \\ & \therefore \mathrm{m}_{\text {orb }} \propto \mathrm{n}\end{aligned}$

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