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Question: Answered & Verified by Expert
The minimum volume of water required to dissolve 0.1 g lead (II) chloride to get a saturated solution ( Ksp of PbCl2=3.2×10-8 ;atomic mass of Pb=207 u ) is:
ChemistryIonic EquilibriumJEE MainJEE Main 2018 (15 Apr)
Options:
  • A 1.798 L
  • B 0.36 L
  • C 17.98 L
  • D 0.18 L
Solution:
1674 Upvotes Verified Answer
The correct answer is: 0.18 L
(Ksp)PbCl2=32×10-9

PbCl2=Pb2+  s   +2Cl- 2s

Ksp= Pb2+ 2Cl-2

Ksp=4s3 = 32×10-9

s3 = 8×10-9

s=2×10-3M

wM.w×1VL=2×10-3

0.1278×1VL=2×10-3

VL=0.1×1000278×2=0.18 L 

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