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Question: Answered & Verified by Expert
The number of moles of NH3, that must be added to 2 L of 0.80MAgNO3 in order to reduce the concentration of Ag+ ions to 5.0×10-8MKformation  for AgNH32+=1.0×108 is __________. (Nearest integer)
[Assume no volume change on adding NH3]
ChemistryChemical EquilibriumJEE MainJEE Main 2021 (27 Aug Shift 1)
Solution:
1687 Upvotes Verified Answer
The correct answer is: 4

Let no. moles of NH3 added =x

Ag+(aq)+2NH3(aq)AgNH32+(aq)

t=0 0.8 x2

t= 5×10-8 x2-1.6 0.8

Keq=AgNH32+Ag+NH32

x2-1.6=0.4

x=4

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