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The pair of gases responsible for acid rain are
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$\mathrm{NO}_2, \mathrm{SO}_2$
Oxides of nitrogen and sulphur are responsible for acid rain.
Due to the presence of $\mathrm{HNO}_3$ and $\mathrm{H}_2 \mathrm{SO}_4$ (strong acids) rain water becomes acidic and rain is called the acid rain.
Due to the presence of $\mathrm{HNO}_3$ and $\mathrm{H}_2 \mathrm{SO}_4$ (strong acids) rain water becomes acidic and rain is called the acid rain.
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