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Question: Answered & Verified by Expert
The products formed in the reaction of phenol with $\mathrm{Br}_2$ dissolved in $\mathrm{CS}_2$ at $0^{\circ} \mathrm{C}$ are
ChemistryAlcohols Phenols and EthersAP EAMCETAP EAMCET 2013
Options:
  • A $o$-bromo, $m$-bromo and $p$-bromophenols
  • B o-bromo and $p$-bromophenols
  • C 2,4,6-tribromo and 2,3,6-tribromophenols
  • D 2,4-dibromo and 2,6-dibromophenols
Solution:
2163 Upvotes Verified Answer
The correct answer is: o-bromo and $p$-bromophenols
Phenol when treated with $\mathrm{Br}_2$ in the presence of non-polar solvent $\mathrm{CS}_2$, it gives only o- and $p$-bromophenols instead the trisubstituted products. Reason for the above observation is supression of phenoxide ion in non-polar solvent. Thus, we get only mono substituted products.

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