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Question: Answered & Verified by Expert
The radius of the largest sphere which fits properly at the centre of the edge of a body centred cubic unit cell is :

(Edge length is represented by 'a')
ChemistrySolid StateJEE MainJEE Main 2019 (11 Jan Shift 2)
Options:
  • A 0.027 a
  • B 0.047 a
  • C $0.134 \mathrm{a}$
  • D 0.067 a
Solution:
2052 Upvotes Verified Answer
The correct answer is: 0.067 a
For bcc

$$

\Rightarrow \mathrm{R}=\frac{\sqrt{3} \mathrm{a}}{4}

$$

$$

\therefore \text { Empty space at edge }=a-2 R=a-\frac{\sqrt{3} a}{2}

$$

$=$ diameter of sphere.

$$

\therefore \quad \mathrm{r}_{\text {sphere }}=\frac{a-\frac{\sqrt{3}}{2} \mathrm{a}}{2}=\left(\frac{2-\sqrt{3}}{4}\right) \mathrm{a}=0.067 \mathrm{a}

$$

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