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The rate constant for a first order reaction is \(60 \mathrm{~s}^{-1}\). How much time will it take to reduce the initial concentration of the reactant to its \(\frac{1}{16^{\text {th }}}\) value?
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\(t=\frac{2 \cdot 303}{k} \log \frac{a}{a / 16}=\frac{2 \cdot 303}{60 \mathrm{~s}^{-1}} \log 16\) \(=4.62 \times 10^{-2} \mathrm{~s}\)
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