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Question: Answered & Verified by Expert
The reaction representing the Mond process for metal refining is ______
ChemistryGeneral Principles and Processes of Isolation of MetalsJEE MainJEE Main 2023 (29 Jan Shift 1)
Options:
  • A Ni+4COΔNi(CO)4
  • B 2KAu(CN)2+ZnΔK2Zn(CN)4+2Au
  • C Zr+2I2ΔZrI4
  • D ZnO+CΔZn+CO
Solution:
1796 Upvotes Verified Answer
The correct answer is: Ni+4COΔNi(CO)4

Mond process for metal refining: In this process, nickel is heated in a stream of carbon monoxide forming a volatile complex, nickel tetracarbonyl:

Ni + 4CO 330 - 350K Ni(CO)4

The carbonyl is subjected to a higher temperature so that it is decomposed giving the pure metal:

Ni(CO)4 450 - 470K Ni + 4CO

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