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Question: Answered & Verified by Expert
The reagent used for the conversion of allyl alcohol into propenal is
ChemistryAldehydes and KetonesAP EAMCETAP EAMCET 2018 (25 Apr Shift 1)
Options:
  • A O3/H2O-Zn dust
  • B DIBAL-H
  • C ClO2Cl2/H3O+
  • D C5H5NH+CrO3Cl-
Solution:
1254 Upvotes Verified Answer
The correct answer is: C5H5NH+CrO3Cl-

The reagent which is used for the conversion of allyl alcohol into propenal is C5H5NH+CrO3Cl- [PCC (pyridinium chlorochromate)].

CH2=CH-CH2-OHAllyl alcoholPCCCH2=CH-CHOPropenal

Here, the reagent used should convert -CH2-OH into -CHO (oxidation) without affecting the double bonds.

PCC

 

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