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Question: Answered & Verified by Expert
The solubility product of AgCl is 1.8 × 1010. Precipitation of AgCl will occur only when equal volumes of which of the following solutions are mixed?
ChemistryIonic EquilibriumJEE Main
Options:
  • A 104 M Ag+ and 104 M Cl
  • B 107 M Ag+ and 107 M Cl
  • C 105 M Ag+ and 105 M Cl
  • D 1010 M Ag+ and 1010 M Cl
Solution:
1444 Upvotes Verified Answer
The correct answer is: 104 M Ag+ and 104 M Cl
After mixing,
Ag+=12 × 104=5 × 10M
Cl =12× 104=5 × 105 M
Q sp = Ag +   Cl = 5 ×  10 5 2 =2.5 ×  10 9
Since, Q sp > K sp precipition takes place

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