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Question: Answered & Verified by Expert
The standard e.m.f of a cell, involving one electron change is found to be 0.591 V at 2oC . The equilibrium constant of the reaction is F=96500 Cmol-1,R=8.314 JK-1mol-1
ChemistryElectrochemistryNEET
Options:
  • A 1.0×1030
  • B 1.0×1015
  • C 1.0×105
  • D 1.0×1010
Solution:
1518 Upvotes Verified Answer
The correct answer is: 1.0×1010
Relation between Keq and Ecell is
E cell o = 2.303RT nF logK eq
E cell o = 0.0591 n logK eq
0.591= 0.0591 1 logK eq
logK eq =10
K eq =1× 10 10

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