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Question: Answered & Verified by Expert
The vapour pressure of benzene at 90°C is 1020 torr. A solution of 15 g of a solute in 58.5 g benzene has a vapour pressure of 990 torr. The molecular weight of the solute is
ChemistrySolutionsNEET
Options:
  • A 78.2
  • B 204.2
  • C 148.2
  • D 226.6
Solution:
1261 Upvotes Verified Answer
The correct answer is: 226.6
Using Raoult's law for relative lowering of vapour pressure as follows
Po-PsPo=w×Mm×W
Here Po=VP or pure solvent, Ps= VP of solution
or 1020-9901020=5×78m×58.5
So m=226.6.

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