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Question: Answered & Verified by Expert
Three alcohols
(i) CH3CH2CH2OH,
(ii) CH3-CHOH-CH3 and
(iii) CH3-C(CH3)(OH)-CH3
were treated seperately with Lucas reagent (Conc. HCl+ZnCl2). What results do you expect at room temperature
ChemistryAlcohols Phenols and EthersNEET
Options:
  • A (i) reacts in about 5 minutes, (ii) reacts in about 15 minutes and (iii) not at all
  • B (iii) reacts immediately, (ii) reacts in about 5 minutes and (i) not at all
  • C (ii) and (iii) react immediately and (i) in about 5 minutes
  • D (i) reacts immediately, (ii) reacts in about 5 minutes and (iii) not at all
Solution:
1537 Upvotes Verified Answer
The correct answer is: (iii) reacts immediately, (ii) reacts in about 5 minutes and (i) not at all
Lucas reagent (Conc. HCl+ZnCl2). is used to distinguish between alcohols tertiary alcohol reacts immediately and gives white turbidity, secondary alcohol reacts in about 5 minutes and primary alcohol do not react.

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