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Question: Answered & Verified by Expert
Three Faraday of electricity is passed through aqueous solutions of AgNO3,NiSO4 and CrCl3 kept in three vessels using inert electrodes. The ratio in mol in which the metals Ag, Ni and Cr will be deposited is
ChemistryElectrochemistryJEE Main
Options:
  • A 1:2:3
  • B 3:2:1
  • C 6:3:2
  • D 2:3:6
Solution:
2389 Upvotes Verified Answer
The correct answer is: 6:3:2
(i) Ag+aq1 mol = 1F3 F+e-Ags1 mol3 mol

(ii) Ni2+aq1 mol = 2F3 F+2e-Nis1 mol32 mol

(iii) Cr 3+ aq 1 mol = 3F +3 e Cr s 1 mol

The required ratio of moles of Ag, Ni and Cr is

3 mol Ag: 3/2 mol Ni : 1 mol Cr or 6 mol Ag : 3 mol Ni : 2 mol Cr.

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