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Question: Answered & Verified by Expert
To what temperature should the hydrogen at $327^{\circ} \mathrm{C}$ be cooled at constant pressure, so that the root mean square velocity of its molecules becomes half of its previous value?
PhysicsKinetic Theory of GasesMHT CETMHT CET 2009
Options:
  • A $-123^{\circ} \mathrm{C}$
  • B $123^{\circ} \mathrm{C}$
  • C $-100^{\circ} \mathrm{C}$
  • D $0^{\circ} \mathrm{C}$
Solution:
1318 Upvotes Verified Answer
The correct answer is: $-123^{\circ} \mathrm{C}$
$v_{\mathrm{ms}} \propto \sqrt{\frac{3 R T}{M}}$
$$
\begin{array}{ll}
\Rightarrow & T \propto v_{\mathrm{rms}}^{2} \\
\Rightarrow & \frac{T_{2}}{T_{1}}=\left[\frac{v_{2}}{v_{1}}\right]^{2}=\frac{1}{4} \\
\Rightarrow & T_{2}=\frac{T_{1}}{4}=\frac{(273+327)}{4} \\
& =150 \mathrm{~K}=-123^{\circ} \mathrm{C}
\end{array}
$$

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