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Question: Answered & Verified by Expert
Two moles of an ideal gas is expanded isothermally and reversibly from 1 litre to 10 litre at 300 K. The enthalpy change (in kJ) for the process is
ChemistryThermodynamics (C)JEE Main
Options:
  • A 11.4 kJ
  • B -11.4 kJ
  • C 0 kJ
  • D 4.8 kJ
Solution:
1305 Upvotes Verified Answer
The correct answer is: 0 kJ
ΔH=ΔE+PV=ΔE+ΔRT=ΔE+RΔT

For isothermal expansion of ideal gas, ΔE=0

ΔE=CvΔT

So ΔH=0+0=0 ΔT=0

putting ΔE=CvΔT,ΔH=CvΔT+RΔT=Cv+RΔT=CpΔT for 1 mole

for n moles, ΔH=nCpΔT=0

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