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Question: Answered & Verified by Expert
Value of standard electrode potential for the oxidation of Clions is more positive than that of water, even then in the electrolysis of aqueous sodium chloride, why is Cloxidized at anode instead of water?
ChemistryElectrochemistryNEET
Options:
  • A The concentration of Clions in the solution is higher than that of water molecules.
  • B Under the conditions of electrolysis of aqueous sodium chloride, oxidation of water at anode requires overpotential hence Clis oxidized instead of water
  • C The standard electrode potential alone determines the species oxidized at the anode.
  • D The concentration of Na⁺ ions in the solution promotes the oxidation of Clions.
Solution:
2009 Upvotes Verified Answer
The correct answer is: Under the conditions of electrolysis of aqueous sodium chloride, oxidation of water at anode requires overpotential hence Clis oxidized instead of water
Correct Option is : (B)
Under the conditions of electrolysis of aqueous sodium chloride, oxidation of water at anode requires overpotential hence Clis oxidized instead of water

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