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Which of the following statements is (are) incorrect?
(i) Percentage ionic character in bond is . (Electronegativity values of and are and respectively)
(ii) From to , the geometry around atom changes drastically.
(iii) The most stable oxidation state for element with atomic number is expected to be
(iv) The ionization energy of is greater than ionization energy of it but lower than ionization energy of K.
Options:
(i) Percentage ionic character in bond is . (Electronegativity values of and are and respectively)
(ii) From to , the geometry around atom changes drastically.
(iii) The most stable oxidation state for element with atomic number is expected to be
(iv) The ionization energy of is greater than ionization energy of it but lower than ionization energy of K.
Solution:
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Verified Answer
The correct answer is:
ii, iii
Ionic character
where, Difference in electro-negativity of bonded atoms.
Geometry for both the species is tetrahedral, as in both 'O' is hybridised
Due to inert pair effect electron do not take part in bond formation, so, most stable oxidation state is
Successive ionization energies are higher for every element. ionization of K happens from configuration which is an inert gas configuration and for it happens from . So, K has higher second ionisation energy than Ca.
where, Difference in electro-negativity of bonded atoms.
Geometry for both the species is tetrahedral, as in both 'O' is hybridised
Due to inert pair effect electron do not take part in bond formation, so, most stable oxidation state is
Successive ionization energies are higher for every element. ionization of K happens from configuration which is an inert gas configuration and for it happens from . So, K has higher second ionisation energy than Ca.
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