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Question: Answered & Verified by Expert
Which of the options correctly represent the basicity for these compounds?

ChemistryAminesTS EAMCETTS EAMCET 2018 (05 May Shift 2)
Options:
  • A i $>$ iii $>$ ii
  • B i $>$ ii $>$ iii
  • C iii $>$ ii $>$ i
  • D iii $>$ i $>$ ii
Solution:
2956 Upvotes Verified Answer
The correct answer is: i $>$ ii $>$ iii


$\mathrm{NO}_2$ have-I effect so, basicity decreases with the closeness of $-\mathrm{NO}_2$ group with $-\mathrm{NH}_2$ group. So, the order will be $(i)>(i i)>($ iit $)$.

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