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Question: Answered & Verified by Expert
Which one of the following conversions involve change in both hybridisation and shape?
ChemistryChemical Bonding and Molecular StructureNEET
Options:
  • A CH4C2H6
  • B NH3NH4+
  • C BF3BF4-
  • D H2OH3O+ 
Solution:
2076 Upvotes Verified Answer
The correct answer is: BF3BF4-
(a)      CH 4 CH 3 - CH 3 4 bp + 0 lp 4 bp 4 bp Hybridisation sp 3 sp 3 sp 3 Structure Tetrahedral Tetrahedral Tetrahedral


(b)      NH 3 NH 4 + 3 bp + 1 lp 4 bp Hybridisation sp 3 sp 3
               Structure              pyramidal        tetrahedral


(c)      BF 3 BF 4 - 3 bp 4 bp Hybridisation sp 2 sp 3 Structure trigonal tetrahedral planar


(d)      H 2 O H 3 O + 2 bp + 2 lp 3 bp + 1 lp Hybridisation sp 3 sp 3 Structure angular Pyramidal

Thus conversion of BF3 into BF4- involves change in both hybridisation and shape.

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