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Question: Answered & Verified by Expert
Which one of the following statements is correct for the reaction?

ChemistryChemical KineticsAP EAMCETAP EAMCET 2012
Options:
  • A Order is two but molecularity is one
  • B Order is one but molecularity is two
  • C Order is one but molecularity is one
  • D Order is two but molecularity is two
Solution:
2815 Upvotes Verified Answer
The correct answer is: Order is two but molecularity is two
For the reaction,
$\begin{aligned} & \mathrm{CH}_3 \mathrm{COOC}_2 \mathrm{H}_5(a q)+\mathrm{NaOH}(a q) \longrightarrow \\ & \mathrm{CH}_3 \mathrm{COONa}(a q)+\mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}(a q)\end{aligned}$
the molecularity is two because two molecules are taking part.
Moreover, rate law for the reaction is,
rate $(r)=k\left[\mathrm{CH}_3 \mathrm{COOC}_2 \mathrm{H}_5\right][\mathrm{NaOH}]$
$\therefore$ Order of reaction is $1+1=2$

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