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Question: Answered & Verified by Expert
Which one of the following statements is wrong?
ChemistryStructure of AtomJEE Main
Options:
  • A de-Broglie's wavelength is given by λ=hmv , were m=mass of the particle,v=group velocity of the particle.
  • B The uncertainty principle is ΔE×Δth4π.
  • C Half-filled and fully-filled orbitals have greater stability due to the greater exchange energy, greater symmetry and more balanced arrangement.
  • D The energy of 2s orbital is less than the energy of 2p orbital in case of hydrogen-like atoms.
Solution:
1606 Upvotes Verified Answer
The correct answer is: The energy of 2s orbital is less than the energy of 2p orbital in case of hydrogen-like atoms.
(i) λ=hp=hmv

(ii) Δx.Δp=h4π

Δx×Δp×dtΔth4π     ΔpΔt=f

fΔx    Δth4πfΔx=ΔE

ΔE.Δth4π

(iii) 3rd statement is true.

(iv) The energy of 2s-orbital and 2p-orbital in case of hydrogen like atoms is equal because they are single electron species.

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