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Question: Answered & Verified by Expert
Why is [NiCl4]2–paramagnetic but [Ni(CO)4] is diamagnetic though both are tetrahedral?
ChemistryCoordination CompoundsNEET
Options:
  • A The presence of Nickel results in stronger ligand-metal bonding, causing diamagnetism in [Ni(CO)4].
  • B The nature of the ligands in [NiCl4]2–is different from [Ni(CO)4], leading to distinct magnetic properties.
  • C [Ni(CO)4] is paramagnetic due to the presence of a strong ligand like CO, while [NiCl4]2–is diamagnetic.
  • D The oxidation state of Ni in [Ni(CO)4] is different from [NiCl4]2–, affecting their magnetic behaviour.
Solution:
1227 Upvotes Verified Answer
The correct answer is: The nature of the ligands in [NiCl4]2–is different from [Ni(CO)4], leading to distinct magnetic properties.
Correct Option is : (B)
The nature of the ligands in [NiCl4]2–is different from [Ni(CO)4], leading to distinct magnetic properties.

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