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Question: Answered & Verified by Expert
Why is the electron gain enthalpy of O or F less negative than that of the succeeding element (S or Cl)?
ChemistryClassification of Elements and Periodicity in PropertiesNEET
Options:
  • A Oxygen and fluorine have smaller atomic sizes.
  • B Oxygen and fluorine have lower effective nuclear charges.
  • C Oxygen and fluorine have higher electron-electron repulsion.
  • D Oxygen and fluorine have larger atomic radii.
Solution:
1107 Upvotes Verified Answer
The correct answer is: Oxygen and fluorine have higher electron-electron repulsion.
The electron gain enthalpy of O or F is less negative than that of the succeeding element (S or Cl) because when an electron is added to O or F, the added electron goes to the smaller n = 2 quantum level and suffers significant repulsion from the other electrons present in this level.

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